Search results for "thermal [correlation function]"
showing 10 items of 1923 documents
Exploring the Coherence of Student Reasoning when Responding to Questionnaires on Thermally Activated Phenomena
2021
Many research results show that students often highlight “mixed-type” reasoning when tackling problematic situations and problems. This reasoning is based on the simultaneous use of common-sense and mere descriptions of facts, perceived as sufficient to build an “explanation” of observed or proposed situations and problems. This fact can be interpreted as a lack of coherence. In this paper, we study the coherence of responses that a sample of undergraduate chemical engineering student give when they are asked to face real-life situations, to create explanations, and to use models in different contexts. We administered open-ended questionnaires before and after a twenty-hour Inquiry-Based wo…
Thermodynamic and electrochemical study of tailor-made crown ethers for redox-switchable (pseudo)rotaxanes
2020
Crown ethers are common building blocks in supramolecular chemistry and are frequently applied as cation sensors or as subunits in synthetic molecular machines. Developing switchable and specifically designed crown ethers enables the implementation of function into molecular assemblies. Seven tailor-made redox-active crown ethers incorporating tetrathiafulvalene (TTF) or naphthalene diimide (NDI) as redox-switchable building blocks are described with regard to their potential to form redox-switchable rotaxanes. A combination of isothermal titration calorimetry and voltammetric techniques reveals correlations between the binding energies and redox-switching properties of the corresponding ps…
Evaluation of multivalency as an organization principle for the efficient synthesis of doubly and triply threaded amide rotaxanes
2014
Mono-, di- and trivalent pseudorotaxanes with tetralactam macrocycle hosts and axles containing diamide binding stations as the guests have been synthesised. Their threading behaviour was analyzed in detail by NMR experiments and isothermal titration calorimetry. An X-ray crystal structure of the monovalent pseudorotaxane confirms the binding motif. Double mutant cycle analysis provides the effective molarities and insight into the chelate cooperativity of multivalent binding. While the second binding event in a trivalent pseudorotaxane exhibits a slightly positive cooperativity, the third binding is nearly non-cooperative. Nevertheless, the enhanced binding affinities resulting from the mu…
Evidence for the Existence of an Effective Interfacial Tension between Miscible Fluids: Isobutyric Acid-Water and 1-Butanol-Water in a Spinning-Drop …
2006
We report definitive evidence for an effective interfacial tension between two types of miscible fluids using spinning-drop tensiometry (SDT). Isobutyric acid (IBA) and water have an upper critical solution temperature (UCST) of 26.3 degrees C. We created a drop of the IBA-rich phase in the water-rich phase below the UCST and then increased the temperature above it. Long after the fluids have reached thermal equilibrium, the drop persists. By plotting the inverse of the drop radius cubed (r(-)(3)) vs the rotation rate squared (omega(2)), we confirmed that an interfacial tension exists and estimated its value. The transition between the miscible fluids remained sharp instead of becoming more…
Thermal and spectroscopic investigation of europium and samarium sulphates hydrates by TG-FTIR and ICP-MS techniques.
2005
The investigation of europium(III) sulphate hydrate and samarium(III) sulphate hydrate was performed by thermal analysis (TG-DTG) and simultaneous infrared evolved gas analysis-Fourier transformed infrared (EGA-FTIR) spectroscopy. The TG, DTG and DTA curves were recorded at the 25-1400 degrees C in the dynamic air atmosphere by TG/DTA analyser. The infrared evolved gas analysis was obtained on the FTIR spectrometer. Eu(2)(SO(4))(3).nH(2)O (n=3.97) and Sm(2)(SO(4))(3).nH(2)O (n=8.11) were analysed, the dehydration and decomposition steps were investigated and the water content was calculated. The formation of different oxysulphates was studied. The trace rare earth elements in Eu and Sm sulp…
A self-sterilizing fluorescent Nanocomposite as versatile material with broad-spectrum Antibiofilm features
2020
Abstract Hematogenous spread of infections from colonized central intravenous catheters or central lines is a long-recognized problem with infection rates of 2 and 6.8 per 1000 days, respectively. Besides, removal of severe microbial colonization of implanted biomaterials is still a challenge and usually requires invasive operations. Hence, on demand self-sterilizing materials are required to avoid explant of colonized biomaterials and improve patient compliance. Moreover, photoluminescence is needed to make trackable biomaterials, which can be easily monitored upon implanting them in the body. Here, we propose the incorporation of near infrared (NIR) sensitive red-emitting carbon nanodot (…
A method to estimate soil moisture from Airborne Hyperspectral Scanner (AHS) and ASTER data: Application to SEN2FLEX and SEN3EXP campaigns
2012
Abstract In this paper the soil moisture is estimated at airborne level and at satellite level by combining remotely sensed images with in situ measurements. At airborne level we process high-resolution images acquired with the Airborne Hyperspectral Scanner (AHS) sensor, and at satellite level we compute images acquired with the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER). The study has been accomplished in the framework of two field campaigns in the Barrax region (Spain): the SEN2FLEX (SENtinel-2 and FLuorescence EXperiment) campaign which was developed in July of 2005 and the SEN3EXP (Sentinel-3 Experiment) campaign which was carried out in June of 2009. The me…
Energy Performance and Indoor Comfort of a 1930s Italian School Building: A case study
2021
Reducing energy consumption in the building tertiary sector, which accounts for a big share of the total energy use (and related CO 2 emissions) at European and Italian level, represent a strong element of safety for the EU-28. On the other hand, it is important to improve the, often overlooked, indoor comfort conditions of Italian schools since they have a significant impact on the well-being, productivity, health and safety of their occupants. Thus, it is appropriate to take into account the combination of both needs, also in light of the climate change scenario, in order to identify adequate improvement measures and justify such economic investment. This paper brings a contribution to th…
Night Thermal Unmixing for the Study of Microscale Surface Urban Heat Islands with TRISHNA-Like Data
2019
International audience; Urban Heat Islands (UHIs) at the surface and canopy levels are major issues in urban planification and development. For this reason, the comprehension and quantification of the influence that the different land-uses/land-covers have on UHIs is of particular importance. In order to perform a detailed thermal characterisation of the city, measures covering the whole scenario (city and surroundings) and with a recurrent revisit are needed. In addition, a resolution of tens of meters is needed to characterise the urban heterogeneities. Spaceborne remote sensing meets the first and the second requirements but the Land Surface Temperature (LST) resolutions remain too rough…
Soil Water Content Diachronic Mapping: An FFT Frequency Analysis of a Temperature–Vegetation Index
2020
Among the indirect estimation approaches of soil water content in the upper layer of the soil, the &ldquo